An electroinitiated cation chain reaction: intramolecular carbon-carbon bond formation between thioacetal and olefin groups.
An electroinitiated cation chain reaction: intramolecular carbon-carbon bond formation between thioacetal and olefin groups.
复制标题
DOI：
10.1002/anie.200705748
复制
发表时间：
2008-03
影响因子：
--
通讯作者：
Kouichi Matsumoto;S. Fujie;Koji Ueoka;Seiji Suga;J. Yoshida
中科院分区：
文献类型：
--
作者：
Kouichi Matsumoto;S. Fujie;Koji Ueoka;Seiji Suga;J. Yoshida
用催化量的ArS（ArSSAr）-+ B（C6 F5）4-处理烯属硫代缩醛，或电解烯属硫代缩醛和ArSSAr的混合物，产生有效的分子内碳-碳键形成（见示意图）。这一转变为电引发阳离子链式反应在有机合成中的应用开辟了广阔的前景。
(Figure Presented) The treatment of an olefinic thioacetal with a catalytic amount of ArS (ArSSAr)-+ B (C 6 F 5) 4-, or the electrolysis of a mixture of an olefinic thioacetal and ArSSAr, gives rise to effective intramolecular carbon-carbon bond formation (see scheme). This transformation opens up great potential for electroinitiated cation chain reactions in organic synthesis.