Fabrication and properties of hollow poly(N‐isopropylacrylamide)‐Ag nanocomposite spheres

Fabrication and properties of hollow poly(N‐isopropylacrylamide)‐Ag nanocomposite spheres
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DOI:
10.1002/pola.23543
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发表时间:
2009-10
期刊:
Journal of Polymer Science Part A
影响因子:
--
通讯作者:
Li-xin Xie;Min Chen;Limin Wu
Li-xin Xie;Min Chen;Limin Wu
中科院分区:
其他
文献类型:
--
作者:
Li-xin Xie;Min Chen;Limin Wu

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本文提出了一种制备中空聚(N-异丙基丙烯酰胺)(PNIPAM)-银纳米复合微球的方法。在该方法中,首先通过一锅法“自去除”工艺合成热敏PNIPAM空心球,然后将其用作Ag +离子的配位和原位还原的载体。结果表明,PNIPAM-Ag纳米复合空心球仍具有典型的热敏性,且具有良好的催化活性,且催化活性随温度的变化具有5个阶段。
This article presents a strategy for the fabrication of hollow poly(N-isopropylacrylamide) (PNIPAM)-Ag nanocomposite spheres. In this approach, the thermosensitive PNIPAM hollow spheres were first synthesized via a one-pot "self-removing" process and then used as supporters for the coordination and in situ reduction of Ag + ions. The results show that these hollow PNIPAM-Ag nanocomposite spheres still have typical thermal sensitivity, and importantly, these spheres have very good and controllable catalytic activity with five stages of variation versus temperature.