A new dirhodium(II) carboxamidate complex as a chiral lewis acid catalyst for enantioselective hetero-Diels-Alder reactions
A new dirhodium(II) carboxamidate complex as a chiral lewis acid catalyst for enantioselective hetero-Diels-Alder reactions
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DOI：
10.1002/anie.200453821
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发表时间：
2004-01-01
影响因子：
16.6
通讯作者：
Hashimoto, S
中科院分区：
文献类型：
--
作者：
Anada, M;Washio, T;Hashimoto, S
在过去的十年里，手性羧酸二氢镝(II)和羧酰胺酯催化剂的非凡能力已经在重氮酮类化合物的一系列不同的对映体选择性金属卡宾转化中被证明。[1]除了在重氮分解中的优势之外，一种在重氮分解中具有空位配位的镝(II)配合物
Over the last decade, the exceptional power of chiral dirhodium (ii) carboxylate and carboxamidate catalysts has been demonstrated in a diverse array of enantioselective metal carbene transformations of diazocarbonyl compounds.[1] Aside from the superiority in diazo decomposition, a dirhodium (ii) complex with vacant coordination sites at the