Zinc(II)-boron(III)-imidazolate framework (ZBIF) with unusual pentagonal channels prepared from deep eutectic solvent
Zinc(II)-boron(III)-imidazolate framework (ZBIF) with unusual pentagonal channels prepared from deep eutectic solvent
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DOI：
10.1039/b920318b
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发表时间：
2010-01-01
影响因子：
4
通讯作者：
Bu, Xianhui
中科院分区：
文献类型：
--
作者：
Chen, Shumei;Zhang, Jian;Bu, Xianhui
第一个锌(II)-硼(III)-咪唑盐多孔材料Zn-2(im)Cl-2[B(im)(4)]（ZBIF-1，im =咪唑盐）集成了两种截然不同的咪唑盐骨架（即具有Zn-im键的ZIF和具有B(im)(4)(-)络合物的BIF）的结构特征，是利用低共熔溶剂的独特化学性质实现的。
The first zinc(II)-boron(III)-imidazolate porous material Zn-2(im)Cl-2[B(im)(4)] (ZBIF-1, im = imidazolate) integrating the structural features of two distinctly different imidazolate frameworks (i.e., ZIFs with the Zn-im linkage and BIFs with B(im)(4)(-) complex) has been realized by utilizing the unique chemistry of deep eutectic solvents.