Syntheses and magnetic properties of a pyrimidyl-substituted nitronyl nitroxide radical and its cobalt(ii) complexes.
Syntheses and magnetic properties of a pyrimidyl-substituted nitronyl nitroxide radical and its cobalt(ii) complexes.
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DOI：
10.1039/c6cc00915h
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发表时间：
2016-03
影响因子：
4.9
通讯作者：
Jian Wang;Jia‐Nan Li;Shaoliang Zhang;Xin-hua Zhao;Dong Shao;Xin-Yi Wang
中科院分区：
文献类型：
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作者：
Jian Wang;Jia‐Nan Li;Shaoliang Zhang;Xin-hua Zhao;Dong Shao;Xin-Yi Wang
合成了一种新的含嘧啶取代基的双齿硝基氮氧化物及其两个钴(II)配合物，并对其进行了表征。首次在硝基氮氧自由基桥联化合物中观察到了场感生的单分子磁体行为。
A new bis-bidentate nitronyl nitroxide radical with a pyrimidyl substituent group and two Co(ii) complexes of this ligand were synthesized and characterized. Field-induced single-molecule magnet behavior was firstly observed in the nitronyl nitroxide radical-bridged complexes.