Pd-catalyzed coupling reaction of allyl and propargyl ethers with chlorosilanes
Pd-catalyzed coupling reaction of allyl and propargyl ethers with chlorosilanes
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DOI：
10.1246/cl.2007.236
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发表时间：
2007-02-05
影响因子：
1.6
通讯作者：
Kambe, Nobuaki
中科院分区：
文献类型：
--
作者：
Naitoh, Yoshitaka;Bando, Fumiaki;Kambe, Nobuaki
介绍了钯催化下由氯硅烷和烯丙基醚合成烯丙基硅烷的方法。在钯催化剂存在下，通过使用苯基或乙烯基格氏试剂，反应在室温下有效地进行。本发明的方法也可以应用于通过使用炔丙基醚合成炔丙基硅烷。
Pd-catalyzed synthesis of allylsilanes from chlorosilanes and allyl ethers is described. The reaction proceeds efficiently at room temperature by the use of phenyl or vinyl Grignard reagent in the presence of palladium catalysts. The present method can also be applied to synthesis of propargylsilanes by the use of propargyl ethers.