Wetting of Argon on CO 2

Wetting of Argon on CO 2
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DOI:
10.1103/physrevlett.82.795
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发表时间:
1998-10
影响因子:
8.6
通讯作者:
G. Mistura;F. Ancilotto;L. Bruschi;F. Toigo
G. Mistura;F. Ancilotto;L. Bruschi;F. Toigo
中科院分区:
物理与天体物理1区
文献类型:
--
作者:
G. Mistura;F. Ancilotto;L. Bruschi;F. Toigo

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We have studied the wetting transition of Ar adsorbed on solid CO2 by means of high-precision adsorption isotherms measured with a quartz microbalance. We observe triple-point wetting. At variance with many theoretical studies based on a model adsorption potential, which predict for this system a genuine prewetting transition around 100K we find that a detailed density-functional calculation employing a more realistic adsorption potential leads to triple-point wetting of Ar on CO2, in good agreement with the experiment.