Updated Abraham model correlations for describing solute transfer into both 2-Pentanol and 3-Methyl-1-butanol based on much larger data sets
Updated Abraham model correlations for describing solute transfer into both 2-Pentanol and 3-Methyl-1-butanol based on much larger data sets
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DOI：
10.1080/00319104.2023.2235709
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发表时间：
2023-07
影响因子：
1.2
通讯作者：
Trisha Kandi;Ramya Motati;Saikiran Motati;Nikita Shanmugam;Amy Zhou;Emily Yao;Catherine Webber;W. Acree
中科院分区：
文献类型：
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作者：
Trisha Kandi;Ramya Motati;Saikiran Motati;Nikita Shanmugam;Amy Zhou;Emily Yao;Catherine Webber;W. Acree
研究了4-叔丁基苯甲酸、3-氯苯甲酸、2-甲基-3-硝基苯甲酸、3-甲基-4-硝基苯甲酸、3,4,5-三甲氧基苯甲酸、间苯二甲酸、3-羟基苯甲酸、邻乙酰乙酰胺、2,4-二羟基苯甲酮、苯甲酸、对乙酰氨基酚和1,4-二氯-2-硝基苯在298.15 K下在2-戊醇中的摩尔分数溶解度。利用实验测量结果，结合已发表的文献数据，计算了2-戊醇溶剂亚伯拉罕模型相关系数的修正方程。还报告了基于包含95个实验数据点的更大数据集的3-甲基-1-丁醇亚伯拉罕模型相关性的修正方程系数。
ABSTRACT Mole fraction solubilities of 4-tert-butylbenzoic acid, 3-chlorobenzoic acid, 2-methyl-3-nitrobenzoic acid, 3-methyl-4-nitrobenzoic acid, 3,4,5-trimethoxybenzoic acid, isophthalic acid, 3-hydroxybenzoic acid, o-acetoacetaniside, 2,4-dihydroxybenzophenone, benzoin, paracetamol, and 1,4-dichloro-2-nitrobenzene in 2-pentanol at 298.15 K. Results of the experimental measurements, combined with published literature data, were used to calculated revised equation coefficients for the Abraham model correlations for the 2-pentanol solvent. Revised equation coefficients are also reported for the 3-methyl-1-butanol Abraham model correlations based on much larger data sets containing 95 experimental data points.