Palladium-Catalyzed Aerobic Oxidative Coupling of Acyl Chlorides with Arylboronic Acids
Palladium-Catalyzed Aerobic Oxidative Coupling of Acyl Chlorides with Arylboronic Acids
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钯催化酰氯与芳基硼酸的有氧氧化偶联
DOI：
10.1002/adsc.201100971
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发表时间：
2012-08-01
影响因子：
5.4
通讯作者：
Wu, Huayue
中科院分区：
文献类型：
--
作者：
Chen, Jiuxi;Peng, Yong;Wu, Huayue
已经开发了钯催化的酰氯与芳基硼酸的有氧氧化偶联的第一个实例，以良好至优异的产率产生了宽范围的芳基苯甲酸酯。该催化体系显示出广泛的官能团耐受性。使用氘标记的初步机理实验表明，氧原子来自双氧。
The first example of a palladium-catalyzed aerobic oxidative coupling of acyl chlorides with arylboronic acids has been developed, leading to a wide range of aryl benzoates in good to excellent yields. This catalytic system shows broad functional group tolerance. Preliminary mechanistic experiments using deuterium labeling showed that the oxygen atom was derived from dioxygen.