A facile one-step synthesis to cross-linked polymeric nanoparticles as highly active and selective catalysts for cycloaddition of CO2 to epoxides.
A facile one-step synthesis to cross-linked polymeric nanoparticles as highly active and selective catalysts for cycloaddition of CO2 to epoxides.
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DOI：
10.1039/b926901k
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发表时间：
2010-05
影响因子：
4.9
通讯作者：
Y. Xiong;Hong Wang;Rongmin Wang;Yunfeng Yan;Bo Zheng;Yunpu Wang
中科院分区：
文献类型：
--
作者：
Y. Xiong;Hong Wang;Rongmin Wang;Yunfeng Yan;Bo Zheng;Yunpu Wang
探索了一种在不添加稳定剂或表面活性剂的情况下，通过传统的自由基共聚法一步合成交联型聚合物纳米粒子的方法。此外，这些纳米粒子在CO(2)与环氧化物的环加成反应中表现出良好的稳定性、活性和选择性，且易于从产物中分离和重复使用。
A very convenient one-step synthesis to cross-linked polymeric nanoparticles by conventional radical copolymerization without the addition of stabilizers or surfactants was explored. Moreover, these nanoparticles exhibited excellent stability, activity and selectivity in the cycloaddition reaction of CO(2) to epoxides and could be separated from the products easily and reused.