Cover Picture: Retro-Cycloaddition Reaction of Pyrrolidinofullerenes (Angew. Chem. Int. Ed. 1/2006)
Cover Picture: Retro-Cycloaddition Reaction of Pyrrolidinofullerenes (Angew. Chem. Int. Ed. 1/2006)
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DOI：
10.1002/anie.200690000
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发表时间：
2006
影响因子：
--
通讯作者：
N. Martín;M. Altable;S. Filippone;Á. Martín-Domenech;L. Echegoyen;C. Cardona
中科院分区：
文献类型：
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作者：
N. Martín;M. Altable;S. Filippone;Á. Martín-Domenech;L. Echegoyen;C. Cardona
如封面图所示，容易制备的吡咯烷基富勒烯的逆环加成提供了定量的原始富勒烯，因此可以作为富勒烯化学中的一种新的保护-去保护方案。N.Martín、L.Echegoyen和他的同事在其第110页以后的通讯中报告了这一有希望的发现，该发现已经允许选择性地分离Sc3N@C80的异构体。
Retro‐cycloadditionof easily prepared pyrrolidinofullerenes affords quantitatively pristine fullerenes, and thus can be used as a new protection‐deprotection protocol in the chemistry of fullerenes, as shown in the cover picture. In their Communication on page 110 ff., N. Martín, L. Echegoyen, and co‐workers report on this promising finding, which has already allowed the selective isolation of theIhconstitutional isomer of Sc3N@C80.