Advent of 2D Rhenium Disulfide (ReS2): Fundamentals to Applications
Advent of 2D Rhenium Disulfide (ReS2): Fundamentals to Applications
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DOI：
10.1002/adfm.201606129
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发表时间：
2017-03-10
影响因子：
19
通讯作者：
Qiao, Shi-Zhang
中科院分区：
文献类型：
--
作者：
Rahman, Mohammad;Davey, Kenneth;Qiao, Shi-Zhang
二硫化铼（ReS 2）是一种二维（2D）VII族过渡金属二硫属化物（TMD）。这是由于结构和振动各向异性，层无关的电学和光学性质，和无金属磁性。这些性质与更广泛使用的VI-TMD族相比是不寻常的，例如，MoS 2、MoSe 2、WS 2和WSe 2。因此，近年来它引起了人们的极大兴趣，现在被用于各种应用，包括固态电子学，催化，能量收集和能量存储。预计ReS 2有可能与VI组的各向同性TMD平行使用，用于所有已知的应用和其他应用。因此，对ReS 2进行审查是非常及时的。在ReS 2的第一篇综述中，我们批判性地分析了现有的合成方法及其优缺点，原子结构和晶格对称性，晶体结构和生长机制，并深入了解了畴和晶界的取向和结构，结构和振动特性的解耦，受晶体缺陷，掺杂和吸附原子吸附影响的各向异性电学，光学和磁学特性，以及不同领域的当代应用。
Rhenium disulfide (ReS2) is a two-dimensional (2D) group VII transition metal dichalcogenide (TMD). It is attributed with structural and vibrational anisotropy, layer-independent electrical and optical properties, and metal-free magnetism properties. These properties are unusual compared with more widely used group VI-TMDs, e.g., MoS2, MoSe2, WS2 and WSe2. Consequently, it has attracted significant interest in recent years and is now being used for a variety of applications including solid state electronics, catalysis, and, energy harvesting and energy storage. It is anticipated that ReS2 has the potential to be equally used in parallel with isotropic TMDs from group VI for all known applications and beyond. Therefore, a review on ReS2 is very timely. In this first review on ReS2, we critically analyze the available synthesis procedures and their pros/cons, atomic structure and lattice symmetry, crystal structure, and growth mechanisms with an insight into the orientation and architecture of domain and grain boundaries, decoupling of structural and vibrational properties, anisotropic electrical, optical, and magnetic properties impacted by crystal imperfections, doping and adatoms adsorptions, and contemporary applications in different areas.