An aryl diimine cobalt( i ) catalyst for carbonyl hydrosilylation
An aryl diimine cobalt( i ) catalyst for carbonyl hydrosilylation
复制标题
用于羰基硅氢加成的芳基二亚胺钴(i)催化剂
DOI：
10.1039/d2cc04089a
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发表时间：
2022
影响因子：
4.9
通讯作者：
Trovitch, Ryan J.
中科院分区：
文献类型：
--
作者：
Sharma, Anuja;So, Sangho;Kim, Jun-Hyeong;MacMillan, Samantha N.;Baik, Mu-Hyun;Trovitch, Ryan J.
通过应用氧化还原无害的芳基二亚胺螯合物，描述了钴催化剂（Ph 2 PPrADI）Co的发现和利用，其表现出高达330 s-1的羰基氢化硅烷化转换频率。该活性被认为是金属催化的羰基氢化硅烷化所报道的最高活性。
Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, (Ph2PPrADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s−1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.