ACIDIC COMPONENTS OF GREEN RIVER SHALE IDENTIFIED BY A GAS CHROMATOGRAPHY-MASS SPECTROMETRY-COMPUTER SYSTEM
ACIDIC COMPONENTS OF GREEN RIVER SHALE IDENTIFIED BY A GAS CHROMATOGRAPHY-MASS SPECTROMETRY-COMPUTER SYSTEM
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DOI：
10.1126/science.165.3894.695
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发表时间：
1969-01-01
期刊：
影响因子：
56.9
通讯作者：
BIEMANN, K
中科院分区：
文献类型：
--
作者：
MURPHY, RC;DJURICIC, MV;BIEMANN, K
由气相色谱仪与质谱仪和计算机连接组成的系统已用于表征格林河页岩的可提取酸性成分。该系统以永久形式累积气相色谱图每一点的质谱，使人们能够观察次要成分和主要成分的质谱。一种微量成分是 6,10,14-三甲基十五烷酸，其鉴定通过合成得到证实。
A system consisting of a gas chromatograph coupled to a mass spectrometer and computer has been used to characterize the extractable acidic components of Green River shale. This system accumulates mass spectra at every point of the gas chromatogram in a permanent form which permits one to observe mass spectra of minor as well as major constituents. One minor component, whose identification was confirmed by synthesis, was 6,10,14-trimethylpentadecanoic acid.