Use of a Diels–Alder reaction to modify thermal expansion properties in charge-transfer cocrystals
Use of a Diels–Alder reaction to modify thermal expansion properties in charge-transfer cocrystals
复制标题
使用狄尔斯-阿尔德反应来改变电荷转移共晶的热膨胀特性
DOI：
10.1039/d2ce01207c
复制
发表时间：
2022
期刊：
影响因子：
3.1
通讯作者：
Hutchins, Kristin M.
中科院分区：
文献类型：
--
作者：
George, Gary C.;Unruh, Daniel K.;Hutchins, Kristin M.
描述了一种改变二向色、电荷转移共晶的热膨胀特性的策略。固态Diels-Alder反应用于共价连接共晶中的相邻分子，与未反应的共晶相比，沿着这些键方向的热膨胀减少了。
A strategy for modifying thermal expansion properties in dichroic, charge-transfer cocrystals is described. A solid-state Diels–Alder reaction is used to covalently connect adjacent molecules in the cocrystal, and thermal expansion along the direction of these bonds is reduced when compared to the unreacted cocrystals.