Organopalladium chemistry in the '60s and '70s
Organopalladium chemistry in the '60s and '70s
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DOI：
10.1039/a909473c
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发表时间：
2000-03-01
影响因子：
3.3
通讯作者：
Tsuji, J
中科院分区：
文献类型：
--
作者：
Tsuji, J
简要介绍了20世纪60 - 70年代有机钯化学的发展历史。有机钯化学已有40年的历史。它诞生于20世纪50年代后期，随着瓦克工艺的发明而诞生。受Wacker反应的启发，我们在20世纪60年代初开始了对Pd化学的研究，并发现了COD（环辛烯）的PdCl（2）络合物与亲碳核试剂的反应，这是通过Pd络合物形成碳-碳键的第一个例子。随后，我们发现了π-烯丙基氯化钯与亲碳试剂的反应，从而打开了π-烯丙基钯化学的新局面。钯（Ⅱ）催化的烯烃和炔烃的氧化羰基化反应和钯（0）催化的烯烃和炔烃的氢羰基化反应是我们实验室的其他发现。本文叙述了本实验室60年代有机钯化学的发展。此外，在20世纪60年代和70年代的其他团体报道的有机钯化学的主要成就进行了总结。
The history of organopalladium chemistry in the 1960s-1970s is briefly outlined. Organopalladium chemistry has a 40 year history. It was born in the late 1950s with the invention of the Wacker process. Inspired by the Wacker reaction, we started our research on Pd chemistry in the early 1960s and discovered the reaction of the PdCl(2) complex of COD (cyclooctadiene) with carbonucleophiles, which was the first example of carbon-carbon bond formation by means of a Pd complex. Then we opened the new held of pi-allylpalladium chemistry by discovering the reaction of pi-allylpalladium chloride with carbonucleophiles. Oxidative carbonylation of alkenes and alkynes mediated by Pd(II) and hydrocarbonylation of alkenes and alkynes catalyzed by Pd(0) were other discoveries made in our laboratory. An account of the development of organopalladium chemistry in our laboratory in the 1960s is presented. In addition, major accomplishments in organopalladium chemistry reported by other groups in the 1960s and 1970s are summarized.