Calixarenes as hosts in aqueous media: inclusion complexation of ferrocene derivatives by a water-soluble calix[6]arene
Calixarenes as hosts in aqueous media: inclusion complexation of ferrocene derivatives by a water-soluble calix[6]arene
复制标题
杯芳烃作为水介质中的主体：水溶性杯[6]芳烃对二茂铁衍生物的包合络合
DOI：
10.1039/c39930001017
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发表时间：
1993
期刊：
影响因子：
--
通讯作者：
A. Kaifer
中科院分区：
文献类型：
--
作者：
Litao Zhang;A. Macías;Tianbao Lu;J. Gordon;G. Gokel;A. Kaifer
三甲基吡啶络合（二茂铁甲基）六氟磷酸铵1·（BF 6），庚基二甲基用电化学和1H NMR技术研究了水溶液中磺化杯[6]芳烃主体与二茂铁甲基溴化铵2·（Br）和二茂铁基甲醇3的反应;杯芳烃主体和所调查的客体之间的结合相互作用类似于在通过环糊精络合有机化合物中操作的那些，环蕃在水介质中为主体。
The complexation of trimethyl(ferrocenylmethyl)ammonium hexafluorophosphate 1·(BF6), heptyldimethyl(ferrocenylmethyl)ammonium bromide 2·(Br) and ferrocenylmethanol 3 by a sulfonated calix[6]arene host was investigated in aqueous media using electrochemical and 1H NMR spectroscopic techniques; the binding interactions between the calixarene host and the surveyed guests are similar to those operating in the complexation of organic compounds by cyclodextrin or cyclophane hosts in aqueous media.
影响因子：
15
作者：
SHINKAI, S;MORI, S;MANABE, O
通讯作者：
MANABE, O