Rhodium-Complex-Catalyzed Addition Reactions of Chloroacetyl Chlorides to Alkynes
Rhodium-Complex-Catalyzed Addition Reactions of Chloroacetyl Chlorides to Alkynes
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DOI：
10.1021/ol802260w
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发表时间：
2008-12-04
期刊：
影响因子：
5.2
通讯作者：
Tanaka, Masato
中科院分区：
文献类型：
--
作者：
Kashiwabara, Taigo;Fuse, Kouichiro;Tanaka, Masato
发现Rh(Acac)(CO)(AsPh3)催化氯乙酰氯衍生物与末端炔的加成反应生成(Z)-1，4-二氯-3-丁烯-2-酮衍生物，在合成精制中表现出不同的反应活性。
The addition reaction of chloroacetyl chloride derivatives with terminal alkynes was found to be catalyzed by Rh(acac)(CO)(AsPh3) to afford (Z)-1,4-dichloro-3-buten-2-one derivatives, which displayed diverse reactivities in synthetic elaboration.