Stepwise guest adsorption with large hysteresis in a coordination polymer {[Cu(bhnq)(THF)2](THF)}n constructed from a flexible hingelike ligand.
Stepwise guest adsorption with large hysteresis in a coordination polymer {[Cu(bhnq)(THF)2](THF)}n constructed from a flexible hingelike ligand.
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DOI：
10.1021/ic060046e
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发表时间：
2006-04
影响因子：
4.6
通讯作者：
Koichi Yamada;Hirokazu Tanaka;Sadahiro Yagishita;K. Adachi;T. Uemura;S. Kitagawa;S. Kawata
中科院分区：
文献类型：
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作者：
Koichi Yamada;Hirokazu Tanaka;Sadahiro Yagishita;K. Adachi;T. Uemura;S. Kitagawa;S. Kawata
用吸附法研究了由柔性铰链配体H2 bhnq [2，2 '-bis（3-hydroxy-1，4-naphthoquinone）]构筑的多孔铜（II）配位聚合物{[Cu（bhnq）（THF）2]（THF）}n（1; THF =四氢呋喃）的可逆汽相变色行为.等温线显示大滞后和逐步的配置文件，这表明发生的客人引起的框架转变。1的动态线圈状行为可以通过客体分子的可逆和选择性掺入引起的氢键相互作用的变化来控制。
Reversible vapochromic behavior of a porous copper(II) coordination polymer {[Cu(bhnq)(THF)2](THF)}n (1; THF = tetrahydrofuran) constructed from a flexible hingelike ligand H2bhnq [2,2'-bis(3-hydroxy-1,4-naphthoquinone)] has been investigated by adsorption measurements. The isotherms show large hysteretic and stepwise profiles, suggesting the occurrence of the guest-induced framework transformation. The dynamic coil-like behavior of 1 can be controlled through the change of the hydrogen-bonding interactions caused by the reversible and selective incorporation of guest molecules.