CuCl2-mediated reaction of [60]fullerene with amines in the presence or absence of dimethyl acetylenedicarboxylate: preparation of fulleropyrroline or aziridinofullerene derivatives.
CuCl2-mediated reaction of [60]fullerene with amines in the presence or absence of dimethyl acetylenedicarboxylate: preparation of fulleropyrroline or aziridinofullerene derivatives.
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DOI：
10.1021/jo402043p
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发表时间：
2013-11
期刊：
影响因子：
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通讯作者：
Hai-Tao Yang;Xi-Chen Liang;Yan-Hong Wang;Yang Yang-Yang;Xiao-qiang Sun;Chun-Bao Miao
中科院分区：
文献类型：
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作者：
Hai-Tao Yang;Xi-Chen Liang;Yan-Hong Wang;Yang Yang-Yang;Xiao-qiang Sun;Chun-Bao Miao
cuc2介导的C60与胺和二甲基乙酰二羧酸酯的三组分反应产生了产率中等的全吡咯啉。此外，cucl2介导的C60与具有强吸电子基团的芳香胺的氧化[2 + 1]反应产生了叠氮二烯和选择性顺式-1-双叠氮二烯富勒烯。
The CuCl2-mediated three-component reaction of C60 with amines and dimethyl acetylenedicarboxylate afforded the fulleropyrrolines in moderate yields. Furthermore, the CuCl2-mediated oxidative [2 + 1] reaction of C60 with aromatic amines bearing a strong electron-withdrawing group provided the aziridinofullerenes and the selective cis-1-bisaziridinofullerenes.