Synthesis, Structure, and Properties of a Dinaphthoazaborine
Synthesis, Structure, and Properties of a Dinaphthoazaborine
复制标题
DOI：
10.1246/cl.2010.612
复制
发表时间：
2010-06-05
影响因子：
1.6
通讯作者：
Kawashima, Takayuki
中科院分区：
文献类型：
--
作者：
Agou, Tomohiro;Arai, Hiroki;Kawashima, Takayuki
合成了一种由两个萘环稠合的1，4-氮杂硼杂环衍生物--二萘并氮杂硼杂环，并通过X-射线晶体学分析确定了其分子结构。紫外维斯吸收光谱和荧光光谱表明，二萘并氮杂硼杂环的HOMO-LUMO能隙比二苯并氮杂硼杂环的HOMO-LUMO能隙减小。电化学测量阐明了增强的电子接受特性的二萘并氮杂硼。
A 1,4-azaborine derivative fused by two naphthalene rings, a dinaphthoazaborine was synthesized, and its molecular structure was revealed by X-ray crystallographic analysis. UV vis absorption and fluorescence spectra of the dinaphthoazaborine indicated a decrease in the HOMO-LUMO energy gap compared with that of dibenzoazaborines. Electrochemical measurements elucidated the enhanced electron-accepting characteristics of the dinaphthoazaborine.