Supramolecular Inclusion Complexes of Fullerenes Using Cyclotriveratrylene Derivatives with Aromatic Pendants

Supramolecular Inclusion Complexes of Fullerenes Using Cyclotriveratrylene Derivatives with Aromatic Pendants
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使用具有芳香侧链的环三藜三烯衍生物制备富勒烯超分子包合物

DOI：
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发表时间：
1998
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影响因子：
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通讯作者：
Koji Yamamoto
Koji Yamamoto
中科院分区：
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文献类型：
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作者：
H. Matsubara;Akio Hasegawa;K. Shiwaku;K. Asano;M. Uno;Shigetoshi Takahashi;Koji Yamamoto

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合成了含芳香侧基的CTV衍生物，用紫外光谱法考察了其对C60和C70的包结能力。具有三个N-甲基吡咯侧基的CTV衍生物显示出C60的最高缔合常数（苯中为48000 dm 3 mol −1）。用单晶X-射线衍射法测定了C60与含有六个苯甲酰基侧基的CTV衍生物的包合物的结构。
CTV derivatives with aromatic pendants were synthesized and their inclusion abilities for C60 and C70 were examined by UV spectroscopy. CTV derivative with three N-methylpyrrole pendants showed the highest association constant for C60 (48000 dm3mol−1 in benzene). The structure of inclusion complex for C60 with CTV derivative which has six benzoyl pendants has been determined by single-crystal X-ray diffraction.