REACTIONS OF CARBONYL SULFIDE AND CARBON-DISULFIDE WITH IRON AND RUTHENIUM COMPLEXES - SYNTHESIS AND REACTIVITY OF DICARBONYL(ETA-2-CARBONYL SULFIDE)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(0)
REACTIONS OF CARBONYL SULFIDE AND CARBON-DISULFIDE WITH IRON AND RUTHENIUM COMPLEXES - SYNTHESIS AND REACTIVITY OF DICARBONYL(ETA-2-CARBONYL SULFIDE)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(0)
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DOI：
10.1021/ic00137a061
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发表时间：
1982-01-01
影响因子：
4.6
通讯作者：
IBERS, JA
中科院分区：
文献类型：
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作者：
GAFFNEY, TR;IBERS, JA
Fe（CO）_2（PPh_3）_3与COS在甲苯中反应生成Fe（CO）_3（PPh_3）_2和SPPh_3。当使用液化COS作为溶剂时，还形成Fe（S2 CO）（CO）2（PPh 3）2。类似的钌配合物Ru（CO）_2（PPh_3）_3与COS反应生成Ru（CO）_2（？）2-COS）（PPh3）2.该COS络合物与另外的COS反应生成Ru-（S2 CO）（CO）2（PPh 3）2，与PPh 3反应生成Ru（CO）3（PPh 3）2和SPPh 3。
The reaction of Fe (CO) 2 (PPh3) 3 with COS intoluene results in the formationof Fe (CO) 3 (PPh3) 2 and SPPh3. When liquefied COS is used as the solvent, Fe (S2CO)(CO) 2 (PPh3) 2 is also formed. The analogous ruthenium complex, Ru (CO) 2 (PPh3) 3, reacts with COS to afford Ru (CO) 2 (?) 2-COS)(PPh3) 2. This COS complex reacts with additional COS to give Ru-(S2CO)(CO) 2 (PPh3) 2 and with PPh3 to giveRu (CO) 3 (PPh3) 2 and SPPh3.