Fish and food safety: Determination of formaldehyde in 12 fish species by SPME extraction and GC-MS analysis
Fish and food safety: Determination of formaldehyde in 12 fish species by SPME extraction and GC-MS analysis
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DOI：
10.1016/j.foodchem.2005.09.089
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发表时间：
2007-01-01
期刊：
影响因子：
8.8
通讯作者：
Mangia, A.
中科院分区：
文献类型：
--
作者：
Bianchi, F.;Careri, M.;Mangia, A.
采用固相微萃取(SPME)-气相色谱-质谱联用法对不同鱼类制品中的甲醛（FA）含量进行了测定。LOD和LOQ值分别为17和28 μ g kg（-1）。通过对12种鱼类（海鱼、淡水鱼和甲壳类）的分析来评估鱼类的质量，揭示了不同的FA水平。对鲜鱼、深冻鱼、罐头鱼、水煮鱼和烤鱼进行了分析；烹调总是使分析物的含量减少。属于加迪科的鱼是FA浓度最高的样品（从6.4 +/- 1.2 mg kg（-1）到293 +/- 26 mg kg(-1)）， 14例中有4例超过了意大利卫生部建议的60 mg kg（-1）的值。在冰上储存也进行了调查，显示在温度约为0℃时FA的产量也适中，最终在所有其他样品中发现FA含量低于22 mg kg（-1）。(c) 2005 Elsevier Ltd版权所有。
The formaldehyde (FA) content in different fish products was evaluated using a solid phase microextraction (SPME)-GC-MS method based on fiber derivatisation with pentafluorobenzyl-hydroxyl-amine hydrochloride. LOD and LOQ values of 17 and 28 mu g kg(-1), respectively were calculated. Fish quality was assessed by the analysis of 12 species (sea-fish, freshwater-fish and crustaceans), revealing variable FA levels. Fresh, deep frozen, canned, boiled and roasted fish were analysed; cooking always produced a decrease in the analyte content. Fish belonging to the Gadidae family were the samples with the highest FA concentration (from 6.4 +/- 1.2 mg kg(-1) to 293 +/- 26 mg kg(-1)), in four cases out of 14 exceeding the value of 60 mg kg(-1) proposed by the Italian Ministry of Health. Storage on ice was also investigated, showing moderate FA production also at temperature around 0 degrees C. FA contents lower than 22 mg kg(-1) were finally found in all the other samples. (c) 2005 Elsevier Ltd. All rights reserved.