Mode II fracture toughening and healing of composites using supramolecular polymer interlayers

Mode II fracture toughening and healing of composites using supramolecular polymer interlayers
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DOI:
10.3144/expresspolymlett.2016.85
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发表时间:
2016-11-01
影响因子:
3.3
通讯作者:
Bosman, A. W.
Bosman, A. W.
中科院分区:
化学3区
文献类型:
--
作者:
Kostopoulos, V.;Kotrotsos, A.;Bosman, A. W.

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本研究的重点是转移的愈合功能的超分子聚合物(SP)的纤维增强复合材料,通过交织。基于氢键表现出自愈合的SP形成膜,并成功地纳入碳纤维复合材料。在Ⅱ型断裂载荷下,研究了SP插层对混杂复合材料面内断裂韧性和随后的愈合能力的影响。的断裂韧性表现出相当大的增加,因为混合复合材料的最大载荷(P-max)大约增加了一倍,因此,模式II层间断裂韧性能量(G(IIC))表现出增加达到近100%相比,参考复合材料。使用外部热量激活愈合组件。测量活化后的P-max和G(IIC)恢复,在第一个愈合周期后,P-max的愈合效率接近85%,G(IIC)接近100%,最终P-max下降到80%,而G(IIC)即使在第四个愈合周期后仍保持在100%左右。在测试过程中的声发射活动进行了监测,并发现由于SP的存在而大大减少。
This study focuses on the transfer of the healing functionality of supramolecular polymers (SP) to fibre reinforced composites through interleaving. SPs exhibiting self-healing based on hydrogen bonds were formed into films and were successfully incorporated into carbon fibre composites. The effect of the SP interleaves on in-plane fracture toughness and the subsequent healing capability of the hybrid composites were investigated under mode II fracture loading. The fracture toughness showed considerable increase since the maximum load (P-max) of the hybrid composite approximately doubled, and consequently the mode II interlaminar fracture toughness energy (G(IIC)) exhibited an increase reaching nearly 100% compared to the reference composite. The healing component was activated using external heat. P-max and G(IIC) recovery after activation were measured, exhibiting a healing efficiency after the first healing cycle close to 85% for P-max and 100% for G(IIC), eventually dropping to 80% for P-max while G(IIC) was retained around 100% even after the fourth healing cycle. Acoustic Emission activity during the tests was monitored and was found to be strongly reduced due to the presence of the SP.