Fluoroform: The polyad at 8–9 μm
Fluoroform: The polyad at 8–9 μm
复制标题
氟仿：8–9 μm 的多聚体
DOI：
10.1016/0022-2852(84)90001-8
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发表时间：
1984
影响因子：
1.4
通讯作者：
G. Guelachvili
中科院分区：
文献类型：
--
作者：
Georges Graner;G. Guelachvili
在相互作用带ν2，ν5和ν3+ν6区域分析了CF_3 H的高分辨傅里叶变换光谱。在模型中先后引入了几种相互作用。在第一步中，只使用ν 5和ν2之间的X-Y Coriolis相互作用，ν 5和ν3+ν 6之间的费米项以及ν3+ν 6之间的（2，2）共振。后来，在ν 5内部增加了thel（2，−1）相互作用，最后在ν 2和ν 5之间增加了偶然的thel（1，−2）相互作用。最后，超过2000个能级被拟合，标准偏差为0.5 × 10−3cm−1。
A high-resolution Fourier transform spectrum of CF3H has been analyzed in the region of the interacting bandsν2,ν5, andν3+ν6. Several interactions were successively introduced in the model. In a first step, only theX-YCoriolis interaction betweenν5andν2, the Fermi term betweenν5andν3+ν6and thel(2, 2) resonance withinν3+ν6were used. Later thel(2, −1) interaction withinν5and finally the accidentall(1, −2) interaction betweenν2andν5were added. Finally, more than 2000 energy levels were fitted with a standard deviation of 0.5 × 10−3cm−1.