Asymmetric synthesis and biosynthetic implications of (+)-fusarisetin A.
Asymmetric synthesis and biosynthetic implications of (+)-fusarisetin A.
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DOI：
10.1002/anie.201202455
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发表时间：
2012-07
影响因子：
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通讯作者：
Jun-Lin Yin;Cheng Wang;Lili Kong;S. Cai;Shuanhu Gao
中科院分区：
文献类型：
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作者：
Jun-Lin Yin;Cheng Wang;Lili Kong;S. Cai;Shuanhu Gao
从马黄素开始，通过一锅转化，包括仿生氧化和分子内Diels-Alder/Roskamp反应，完成了(+)- fusarissetin A的不对称合成。根据对马黄素氧化的研究，过氧镰刀菌素被认为是一种可行的生物合成中间体。
Starting from equisetin, the asymmetric synthesis of (+)-fusarisetin A has been accomplished in a one-pot transformation including a biomimetic oxidation and an intramolecular Diels-Alder/Roskamp reaction. Peroxyfusarisetin is proposed as a plausible biosynthetic intermediate based on studies of the oxidation of equisetin.