A new phenylpropanoid glucoside and a chain compound from the roots of Allium tuberosum

A new phenylpropanoid glucoside and a chain compound from the roots of Allium tuberosum
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一种新的苯丙素葡萄糖苷和来自马铃薯根的链状化合物

DOI:
10.1080/14786419.2016.1212034
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发表时间:
2017-01-01
影响因子:
2.2
通讯作者:
Ding, Zhong-Tao
Ding, Zhong-Tao
中科院分区:
化学3区
文献类型:
--
作者:
Fang, Yun-Shan;Liu, Shi-Xi;Ding, Zhong-Tao

文献摘要

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从韭菜根中分得一个新的苯丙素苷类化合物tuberosinine D(1)和一个链状化合物(Z)-11R,12 S,13 S-三羟基-9-十八烯酸酯(2)。通过电子圆二色性的计算与实验结果的比较,确定了1的绝对构型。首次用改进的Mosher方法确定了2的绝对构型。
A new phenylpropanoid glucoside tuberosinine D (1) and a chain compound (Z)-11R,12S,13S-trihydroxy-9-octadecenoate (2) were isolated from the roots of Allium tuberosum. The absolute configuration of 1 was established by comparing of experimental and calculated electronic circular dichroism. The absolute configuration of 2 was determined using the modified Mosher's method for the first time.