N-BOC-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines
N-BOC-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines
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DOI：
10.1021/ja0475398
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发表时间：
2004-07-07
影响因子：
15
通讯作者：
Tomioka, K
中科院分区：
文献类型：
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作者：
Kuriyama, M;Soeta, T;Tomioka, K
研究了N-Boc-L-valine连接的氨基膦(I)催化剂在N-PROH中催化空间调谐亚胺与芳基硼氧杂多胺的不对称芳基化反应。用于亚胺的空间调谐的TM基团可转化为其他官能团，可用作Carbon−碳键形成偶联反应的关键立足点。
A catalytic asymmetric arylation of sterically tuned imines with arylboroxines was developed by usingN-Boc-l-valine-connected amidomonophosphane rhodium(I) catalyst inn-PrOH. The TMS group used for the steric tuning of imines is convertible to other functionalities that are applicable as a key foothold for the carbon−carbon bond-forming coupling reactions.