Iodine-Mediated Thiolation of Substituted Naphthols/Naphthylamines and Arylsulfonyl Hydrazides via C(sp2)-H Bond Functionalization
Iodine-Mediated Thiolation of Substituted Naphthols/Naphthylamines and Arylsulfonyl Hydrazides via C(sp2)-H Bond Functionalization
复制标题
DOI：
10.1021/jo501778h
复制
发表时间：
2014-11-07
影响因子：
3.6
通讯作者：
Huang, Guosheng
中科院分区：
文献类型：
--
作者：
Kang, Xing;Yan, Rulong;Huang, Guosheng
发展了一种碘介导的萘酚/萘胺和芳磺酰肼巯基化反应的直接方法，通过C-S键的形成和S-N/S-O键的断裂，实现了萘酚/萘胺和芳磺酰肼的巯基化反应。在这种转化中，可以轻松地以中等至良好的产率获得一系列有价值的硫醚。
A direct method has been developed for iodine-mediated thiolation of naphthols/naphthylamines and arylsulfonyl hydrazides through the formation of C-S bond and cleavage of S-N/S-O bonds. In this transformation, a range of valuable thioethers are easily achieved in moderate to good yields.