Facile deposition of [60]fullerene on the electrode by electrochemical oxidative polymerization of thiophene.

Facile deposition of [60]fullerene on the electrode by electrochemical oxidative polymerization of thiophene.
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通过噻吩的电化学氧化聚合在电极上轻松沉积[60]富勒烯。

DOI:
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发表时间:
2003
影响因子:
4.9
通讯作者:
S. Shinkai
S. Shinkai
中科院分区:
化学2区
文献类型:
--
作者:
Tsukasa Hatano;M. Takeuchi;A. Ikeda;S. Shinkai

文献摘要

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研究发现,以阴离子杯[8]芳烃包埋的[60]富勒烯可以通过乙二氧基噻吩电催化氧化聚合反应生成[60]富勒烯:得到的电极在可见光照射下产生一个光电波(约100nA·cm~(-2))。
It was found that [60]fullerene encapsulated in anionic calix[8]arenes can be readily deposited by electrochemical oxidative polymerization of ethylenedioxythiophene: the resultant electrode generates a photocurrent wave (ca. 100 nA cm(-2)) in response to visible light irradiation.