Cation-cation interactions between neptunyl(VI) units.
Cation-cation interactions between neptunyl(VI) units.
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DOI:
10.1021/ic3009305
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发表时间:
2012-06
影响因子:
4.6
通讯作者:
Shuao Wang;Juan Diwu;E. Alekseev;L. Jouffret;W. Depmeier;T. Albrecht‐Schmitt
中科院分区:
文献类型:
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作者:
Shuao Wang;Juan Diwu;E. Alekseev;L. Jouffret;W. Depmeier;T. Albrecht‐Schmitt
The boric acid flux reaction of NpO(2)(ClO(4))(2) with NaClO(4) affords Na[(NpO(2))(4)B(15)O(24)(OH)(5)(H(2)O)](ClO(4))·0.75H(2)O (NaNpBO-1). NaNpBO-1 possesses a layered structure consisting of double neptunyl(VI) borate sheets bridged by another Np(VI) site through cation-cation interactions. The sole presence of Np(VI) in NaNpBO-1 is supported by absorption and vibrational spectroscopy.