A fluorescein-based probe with high selectivity and sensitivity for sulfite detection in aqueous solution

A fluorescein-based probe with high selectivity and sensitivity for sulfite detection in aqueous solution
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一种具有高选择性和高灵敏度的荧光素探针,用于水溶液中亚硫酸盐的检测

DOI:
10.1016/j.snb.2013.08.007
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发表时间:
2013-11-01
影响因子:
8.4
通讯作者:
Du, Yuguo
Du, Yuguo
中科院分区:
化学1区
文献类型:
--
作者:
Ma, Xing;Liu, Chunxia;Du, Yuguo

文献摘要

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利用SO32促进的乙酰丙基裂解和荧光素的同步生成,建立了一种用于亚硫酸盐检测的“开启”荧光素探针。该探针对其他14种阴离子具有较高的SO32选择性,在含有CH3CN (1%, v/v)的水介质中检测限为0.80 mg/L。该探针成功地应用于白葡萄酒中亚硫酸盐的检测。(C) 2013年Elsevier B.V.出版
A "turn-on" fluorescein-based probe for sulfite detection has been established employing SO32- promoted levulinyl cleavage and concurrent generation of fluorescein. The synthesized probe exhibits high SO32- selectivity over fourteen other anion ions, and the satisfactory detection limit was 0.80 mg/L in aqueous media containing co-solvent CH3CN (1%, v/v). The probe is successfully applied for the detection of sulfite in white wine. (C) 2013 Published by Elsevier B.V.