K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ]: the first example of a heterometallic extended metal atom node (HEMAN)
K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ]: the first example of a heterometallic extended metal atom node (HEMAN)
复制标题
K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ]:异金属扩展金属原子节点的第一个示例 (HEMAN)
DOI:
10.1039/c6dt03659g
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发表时间:
2016
影响因子:
4
通讯作者:
Berry, John F.
中科院分区:
文献类型:
--
作者:
Dolinar, Brian S.;Kozimor, Stosh A.;Berry, John F.
We present the synthesis, structure, and electrochemistry of K3[Mo2(SNO5)4Cl]3[Mo2(SNO5)4] (1, HSNO5 = monothiosuccinimide), the first example of a heterometallic extended metal atom node (HEMAN). The HEMAN consists of two perpendicular, intersecting lines of metal atoms formed by three [Mo2(SNO5)4Cl]− units and one [Mo2(SNO5)4] unit tethered together by K+ ions.