Metal ion-induced self-assembly of functionalized 2,6-oligopyridines. 1. Ligand design, synthesis, and characterization
Metal ion-induced self-assembly of functionalized 2,6-oligopyridines. 1. Ligand design, synthesis, and characterization
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金属离子诱导功能化 2,6-寡聚吡啶的自组装。
DOI：
10.1021/ja00060a029
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发表时间：
1993
影响因子：
15
通讯作者：
M. Keshavarz
中科院分区：
文献类型：
--
作者：
K. Potts;K. G. Raiford;M. Keshavarz
利用α-氧代烯酮二硫代缩醛和烯醇化物化学的合成序列已被开发用于制备新的官能化联吡啶、三联吡啶、四联吡啶、喹吡啶、六联吡啶、七联吡啶、八联吡啶、诺维吡啶和十联吡啶。以中等至良好的产率获得，这些低聚吡啶的特征在于分析和光谱数据，对于六吡啶，通过X射线晶体学
Synthetic sequences utilizing α-oxoketene dithioacetal and enolate chemistry have been developed for the preparation of new functionalized bipyridines, terpyridines, quaterpyridines, quinquepyridines, sexipyridines, septipyridines, octipyridines, novipyridines, and decipyridines. Obtained in moderate to good yields, these oligopyridines were characterized by analytical and spectral data and, for sexipyridine, by X-ray crystallography