Organic P-N Junction Solar Cells

Organic P-N Junction Solar Cells
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有机 P-N 结太阳能电池

DOI:
10.1080/00268948308073540
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发表时间:
1983
期刊:
影响因子:
--
通讯作者:
G. Chamberlain
G. Chamberlain
中科院分区:
--
文献类型:
--
作者:
G. Chamberlain

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摘要制备了一系列固态有机太阳能电池,并在模拟太阳光下进行了测试。光伏效应与在三苯甲烷染料(n型)和汞染料(p型)之间的界面处形成整流结一致。最有效的装置是在派热克斯玻璃上用铟锡氧化物/孔雀石绿色/苯并噻唑-若丹宁汞/Au薄层制成的夹层。在没有空气的情况下,将电池暴露于氯蒸气将阳光效率提高到0.12%。对光电流作用谱、整流和电容的研究为光伏能量转换过程提供了机理信息。
Abstract A number of solid state organic solar cells have been prepared and tested in simulated sunlight. Photovoltaic effects were consistent with the formation of a rectifying junction at the interface between a triphenylmethane dye (n-type) and a merocyanine dye (p-type). The most efficient device consisted of a sandwich of thin layers of indium-tin oxide/malachite green/a benzothiazole-rhodanine merocyanine/Au on Pyrex. Exposure of the cell to chlorine vapour in the absence of air improved the sunlight efficiency to 0.12%. Investigations of the photocurrent action spectrum, rectification and capacitance have given mechanistic information on the photovoltaic energy conversion processes.