Intermolecular Vibrational Energy Transfers in Melts and Solutions
Intermolecular Vibrational Energy Transfers in Melts and Solutions
复制标题
熔体和溶液中的分子间振动能量转移
DOI：
10.1063/1674-0068/29/cjcp1602028
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发表时间：
2016-08
影响因子：
1
通讯作者：
Zheng Jun-rong
中科院分区：
文献类型：
--
作者：
Shen Yu-neng;Jiang Bo;Ge Chuan-qi;Deng Gang-hua;Chen Hai-long;Yang Xue-ming;Yuan Kai-jun;Zheng Jun-rong
Resonant and nonresonant intermolecular vibrational energy transfers in Gdm-SCN/KSCN=1/1, GdmSCN/KS13CN=1/1 and GdmSCN/KS13C15N=1/1 mixed crystals in melts and in aqueous solutions are studied with the two dimensional infrared spectroscopy. The energy transfers in the samples are slower with a larger energy donor/acceptor gap, independent of the Raman spectra. The energy gap dependences of the nonresonant energy transfers cannot be described by the phonon compensation mechanism. Instead, the experimental energy gap dependences can be quantitatively described by the dephasing mechanism. Temperature dependences of resonant and nonresonant energy transfer rates in the melts are also consistent with the prediction of the dephasing mechanism. The series of results suggest that the dephasing mechanism can be dominant not only in solutions, but also in melts (pure liquids without solvents), only if the molecular motions (translations and rotations) are much faster than the nonresonant energy transfer processes.
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影响因子：
4.4
作者：
E. Heilweil;M. Casassa;R. Cavanagh;J. Stephenson
通讯作者：
E. Heilweil;M. Casassa;R. Cavanagh;J. Stephenson
影响因子：
4.4
作者：
M. Tuckerman;B. Berne
通讯作者：
M. Tuckerman;B. Berne
影响因子：
56.9
作者：
Zhaohui Wang;Andrei V. Pakoulev;D. Dlott
通讯作者：
Zhaohui Wang;Andrei V. Pakoulev;D. Dlott
DOI：
10.1063/1.3458825
发表时间：
2010-07
期刊：
The Journal of chemical physics
影响因子：
--
作者：
Hongtao Bian;Xiewen Wen;Jiebo Li;Junrong Zheng
通讯作者：
Hongtao Bian;Xiewen Wen;Jiebo Li;Junrong Zheng
DOI：
10.1021/jp3053373
发表时间：
2013-04
期刊：
The journal of physical chemistry. B
影响因子：
--
作者：
Jiebo Li;Hongtao Bian;Hailong Chen;Xiewen Wen;B. T. Hoang;Junrong Zheng
通讯作者：
Jiebo Li;Hongtao Bian;Hailong Chen;Xiewen Wen;B. T. Hoang;Junrong Zheng