Molecular and Magnetooptical Spectroscopy (Chemistry)

分子和磁光光谱（化学）

• 批准号: 8700754
• 负责人: Paul Schatz
• 金额: $ 18.5万
• 依托单位: University of Virginia Main Campus
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1987
• 资助国家: 美国
• 起止时间: 1987-07-15 至 1989-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8700754&HistoricalAwards=false
• 关键词: Molecular; Magnetooptical; Spectroscopy; Chemistry

This grant in Experimental Physical Chemistry supports research of Professor Paul N. Schatz in both experimental and theoretical spectroscopy. His current research program is designed to meet the need for basic electronic structural information about the ground and excited states of molecular, ionic, mixed-valent and radical species. This information is needed to test theoretical models of these systems and to help interpret their chemical properties and reactivities. The PI has also pioneered in the use of the Synchrotron light source in basic chemical research. In forthcoming research Dr. Schatz will use magnetic circular dichroism, absorption and emission spectroscopy to study matrix isolated species over a wide spectral range from about 1500nm in the near infrared through the visible and ultraviolet to about 120nm in the vacuum ultraviolet. Synchrotron based vacuum ultraviolet measurements will be conducted using a self-contained matrix isolation superconducting magnetic system. Mixed-valence species will be studied theoretically and mixed-valent precursors of the "organic metals" will be studied spectroscopically.

实验物理化学的这项资助支持以下研究： Paul N.沙茨在实验和理论 谱 他目前的研究计划旨在满足 需要有关地面的基本电子结构信息， 分子、离子、混合价和自由基物种的激发态。 需要这些信息来测试这些系统的理论模型 并帮助解释它们的化学性质和反应性。 的 PI还率先使用同步加速器光源， 基础化学研究。 在即将进行的研究中，Schatz博士将使用磁性圆 二向色性、吸收和发射光谱来研究基质 分离的物种在宽光谱范围内从约1500nm的， 近红外线通过可见光和紫外线到约120 nm的 真空紫外线 基于同步加速器的真空紫外测量 将使用独立的基质隔离进行 超导磁系统 混合价态物种将被研究 理论上，“有机金属”的混合价前体将 用光谱学研究。