Ultraviolet and Infrared Studies of Photochemically Generated Matrix-Isolated Species

光化学产生的基质隔离物质的紫外线和红外线研究

• 批准号: 8804804
• 负责人: Susan Collins
• 金额: $ 2.25万
• 依托单位: California State University-Northridge
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1988
• 资助国家: 美国
• 起止时间: 1988-09-01 至 1990-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8804804&HistoricalAwards=false
• 关键词: Ultraviolet; Infrared; Studies; Photochemically; Generated

This research, part of the Experimental Physical Chemistry Program, is designed to study photochemistry of several prototypical systems at low temperatures. The research will elucidate the mechanisms of photolysis, identify intermediate species and elucidate their energy levels. Three systems are to be studied including the photolysis of dimethylacetylene, photoreactions of 1,4-diene systems and pseudo Jahn Teller interactions in phthalazine-alcohol complexes.

这项研究是实验物理化学计划的一部分，旨在研究几个原型系统在低温下的光化学。这项研究将阐明光解的机理，鉴定中间物种并阐明它们的能级。研究了三个体系：二甲基乙炔的光解、1，4-二烯体系的光反应和杂氮-醇配合物中的假Jahn-Teller相互作用。