Fabrication and Evaluation of Organized Molecular Assembliesof Electroactive Polymers

电活性聚合物有序分子组装体的制备和评价

• 批准号: 9023867
• 负责人: Michael Rubner
• 金额: --
• 依托单位: Massachusetts Institute of Technology
• 依托单位国家: 美国
• 项目类别: Continuing grant
• 财政年份: 1991
• 资助国家: 美国
• 起止时间: 1991-07-01 至 1993-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9023867&HistoricalAwards=false
• 关键词: Fabrication; Evaluation; Organized; Molecular; Assembliesof

This program will attempt, purportedly for the first time, to fabricate thin film heterostructures of electroactive polymers in which the structure and architecture of the films are manipulated at the molecular level. The new materials formed from these complex molecular assemblies will be studied for the determination of their optical properties, electrical properties, which will provide new insights into the fundamental behavior of electroactive polymers and reveal new opportunities for thin film devices and microelectronic sensors. The overall objectives of the research is to fabricate, characterize, and evaluate novel, highly ordered, molecular assemblies of electroactive polymers. Specifically, .e monolayer forming systems based on electroactive polymers will be developed and utilized in conjunction with previously developed electroactive monolayers to fabricate complex heterostructures comprised of functionally distinct layers arranged at the molecular level to achieve specific electrical, optical, or chemical response. Particular attention will be paid to monolayer forming systems that provide the highest level of order and orientation of the electroactive polymer component and a high degree of processing flexibility.

据称，该计划将首次尝试 制备电活性聚合物的薄膜异质结构 其中膜的结构和体系结构被 在分子水平上操纵。 形成的新材料 从这些复杂的分子组装将被研究， 它们的光学性质、电学性质 属性，这将提供新的见解， 电活性聚合物的基本行为，并揭示新的 薄膜器件和微电子器件的发展机遇 传感器. 研究的总体目标是制造， 表征和评估新型的高度有序的分子 电活性聚合物的组装体。 具体来说，e 基于电活性聚合物的单层形成系统将 开发和利用与以前 开发电活性单层来制造复合物 由功能不同的层组成的异质结构 在分子水平上排列， 电、光或化学反应。 特别 将关注单层形成系统，其 提供最高水平的秩序和方向， 电活性聚合物组分和高度的 加工灵活性。