Syntheses and Photochemistry of Electron Rich Complexes with Nitrogen Donors

氮供体富电子配合物的合成和光化学

• 批准号: 9107610
• 负责人: Mary Rakowski DuBois
• 金额: $ 5.93万
• 依托单位: University of Colorado at Boulder
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1991
• 资助国家: 美国
• 起止时间: 1991-07-15 至 1993-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9107610&HistoricalAwards=false
• 关键词: Syntheses; Photochemistry; Electron; Rich; Complexes

This project will focus on a new area of research for Dr. Rakowski-DuBois. She will spend a month at the beginning of the project interacting with research groups which are active in the area on metal nitrogen chemistry. She will obtain a better sense of properties and potential reactions of these complexes and get a better perspective on important problems in organometallic chemistry. During this period she will have access to original material not readily available at the University of Colorado. Following this, a major portion of the project period will be spent in her own laboratory where syntheses of new metalorgano-nitrogen complexes and their reactions can be explored most efficiently. She will renew her her synthetic expertise with hands-on research during this period, and will acquaint herself with new instrumentation, software, and new experimental techniques. In the latter part of this project she will spend an extended period of time in laboratories at the University of Texas gaining experience in photochemical techniques and exploring a collaborative investigation of organometallic nitrogen and oxo complexes and clusters. The remaining period of this project will be devoted to developing new techniques and collaborations in her research group at Colorado. %%% This Career Advancement Award will support activities that will expand Dr. Mary Rakowski-DuBois' research career potential. The scope and intent of this award will provide for the development of new skills in areas that will expand her research programs and develop innovative research methods in collaborations with other investigators.

这个项目将集中在Rakowski-DuBois博士的一个新的研究领域。在项目开始时，她将花一个月的时间与活跃在金属氮化学领域的研究小组进行互动。她将对这些配合物的性质和潜在反应有更好的认识，并对有机金属化学中的重要问题有更好的看法。在此期间，她将有机会接触到科罗拉多大学没有的原始材料。在此之后，项目期间的主要部分将在她自己的实验室中度过，在那里可以最有效地探索新的金属有机氮配合物的合成及其反应。在此期间，她将通过动手研究来更新自己的合成专业知识，并将熟悉新的仪器，软件和新的实验技术。在该项目的后半部分，她将在德克萨斯大学的实验室中度过一段较长的时间，以获得光化学技术方面的经验，并探索有机金属氮和氧配合物和簇的合作研究。该项目的剩余时间将致力于开发新技术，并与她在科罗拉多的研究小组合作。该职业发展奖将支持拓展Mary Rakowski-DuBois博士研究职业潜力的活动。该奖项的范围和意图将提供新技能的发展，这将扩大她的研究项目，并与其他研究人员合作开发创新的研究方法。