Analytical Pulse Voltammetry

该项目属于分析和表面化学的一般领域，以及电分析化学的子领域。在这项为期两年的持续资助期间，奥斯特杨教授和她的学生将把脉冲伏安技术应用于苯二氮类药物的定量、离子与环糊精的相互作用的研究以及薄膜的电解形成。将要研究的具体实验体系包括环糊精对二茂铁羧酸和血红素的络合作用，非水介质中苯二氮类化合物分析方法的发展，单分散球在电化学体系质量传输研究中的新应用，以及BaCuO超导体的电结晶。本研究将扩大基础电化学的知识库，拓宽基础电化学的实际应用。将从这项工作中受益的相关领域包括药物分析、酶模拟和高温超导材料。

This project is in the general area of analytical and surface chemistry and in the subfield of electroanalytical chemistry. During the tenure of this two-year continuing grant, Professor Osteryoung and her students will apply pulse voltammetric techniques to the quantification of benzodiazepines, to the study of the interactions of ions with cyclodextrins, and to the electrolytic formation of thin films. Specific experimental systems to be investigated include complexation of ferrocenecarboxylic acid and heme entities by cyclodextrins, development of methods for benzodiazepine analysis in nonaqueous media, novel applications of monodisperse spheres to the study of mass transport in electrochemical systems, and electrocrystallization of Ba-Cu-O superconductors. %%% This research will expand the knowledge base and broaden practical utilization of fundamental electrochemistry. Related areas that will benefit from this work include pharmacoanalysis, enzyme modeling, and high temperature superconducting materials.