Unusual Structure in Polyphenyl Aromatic Molecules

聚苯芳香族分子的异常结构

• 批准号: 9707958
• 负责人: Robert Pascal
• 金额: $ 34.75万
• 依托单位: Princeton University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1997
• 资助国家: 美国
• 起止时间: 1997-06-01 至 2000-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9707958&HistoricalAwards=false
• 关键词: Unusual; Structure; Polyphenyl; Aromatic; Molecules

The foci of this research are the preparation and characterization of a variety of linear perphenyl acenes and numerous macrocyclic and branched polyphenyl aromatics. The key steps in the syntheses of the former class are Diels-Alder reactions of polyphenyl arynes and dienes. Syntheses of the latter compounds will depend heavily on the reactions of aromatic alkynes and polyphenyl arynes with an array of polyphenylcyclopentadienones. The ease of synthesis, ease of derivatization, well-defined conformation, great stability and excellent solubility properties make the compounds excellent candidates for study and application. Applications for use in electrochemical, photochemical and host-guest purposes will be probed. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Robert A. Pascal of the Department of Chemistry at Princeton University. Professor Pascal will focus his work on the preparation and characterization of very large polyphenyl aromatic compounds. These compounds have potential for having great value in electrochemical, photochemical and host-guest applications.

本研究的重点是制备和表征的一个 各种直链并苯和许多大环和支链 聚苯芳族化合物。 前一类综合的关键步骤 是聚苯芳炔和二烯的Diels-Alder反应。 的合成 后一种化合物将严重依赖于芳族化合物的反应， 炔和多苯基芳炔， 聚苯基环烯酮 合成的简易性， 衍生化，明确的构象，良好的稳定性和优异的 溶解性使化合物成为研究的极好候选物 和应用 在电化学、光化学、 和主客目的将被探测。 有了这个更新奖， 合成有机计划是支持博士罗伯特A。 他是普林斯顿大学化学系的帕斯卡。 教授 帕斯卡将把他的工作重点放在制备和表征 非常大的多苯基芳香族化合物。 这些化合物具有潜在的 在电化学、光化学、主客体化学等方面具有重要的应用价值 应用.