Upgrade of an 8.46 Tesla NMR Instrument

该奖项由化学研究仪器和设施 CRIF计划和多学科活动办公室（OMA）将 协助麦迪逊的威斯康星州大学化学系 升级现有的布鲁克AM-360 8.46特斯拉核磁 共振（NMR）光谱仪。该设备将加强研究， 涉及有机金属反应机理的许多领域， 有机锂试剂，有机硅化学，电子转移 自由基阳离子，均相催化剂的表征，以及 液体中分子结构和动力学的基础研究。 核磁共振（NMR）光谱是最强大的工具， 化学家用来阐明分子结构的仪器。 它用于识别未知物质，表征特定物质， 分子内原子的排列，并研究 溶液中分子间的相互作用获得最新技术 核磁共振谱是化学家进行前沿研究的基础 research.这些NMR研究的结果在以下领域是有用的， 如聚合物、催化剂和生物学。

This award from the Chemistry Research Instrumentation and Facilities (CRIF) Program and the Office of Multidisciplinary Activities (OMA) will assist the Department of Chemistry at University of Wisconsin at Madison to upgrade an existing Bruker AM-360 8.46 tesla nuclear magnetic resonance (NMR) spectrometer. This equipment will enhance research in a number of areas involving mechanism of organometallic reactions, organolithium reagents, organosilicon chemistry, electron transfer in radical cations, characterization of homogeneous catalysts, and fundamental studies of molecular structures and dynamics in liquids. Nuclear Magnetic Resonance (NMR) spectroscopy is the most powerful tool available to chemists for the elucidation of the structure of molecules. It is used to identify unknown substances, characterize specific arrangements of atoms within molecules, and to study the dynamics of interactions between molecules in solution. Access to state-of-the-art NMR spectrometry is essential to chemists who are carrying out frontier research. The results from these NMR studies are useful in the areas such as polymers, catalysis, and in biology.