U.S.-German Cooperative Research: Energy and Charge Transfer with Functionalized Phenols -- Time-Resolved Photochemical and Radiation Chemical Experiments

美德合作研究：功能化酚的能量和电荷转移——时间分辨光化学和辐射化学实验

• 批准号: 9726193
• 负责人: Dirk Guldi
• 金额: $ 1.85万
• 依托单位: University of Notre Dame
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1998
• 资助国家: 美国
• 起止时间: 1998-02-15 至 2001-01-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9726193&HistoricalAwards=false
• 关键词: U.S.; German; Cooperative; Research; Energy

The cooperative research program (`Energy and Charge Transfer with Functionalized Phenols-Time-Resolved Photochemical and Radiation Chemical Experiments`) is intended to initiate a collaboration between the Notre Dame Radiation Laboratory (NDRL) and the Interdisciplinary Research Group on Time Resolved Spectroscopy (IAG) at the University of Leipzig. Until now, the two laboratories had been independently using two of the most powerful time-resolved spectroscopic techniques (viz., pulse radiolysis and flash photolysis), but with different detection methods: Fourier Transformed Electron Paramagnetic Resonance at IAG and Raman spectroscopy and conductivity measurements at NRDL. The combination of the unique methodologies along with the IAG's outstanding expertise in the field of sterically hindered phenols and the NDRL's strong background in charge and energy transfer processes promises a significant advancement in the free-radical related chemistry of an important class of chemical compounds.

该合作研究项目(‘官能化酚类的能量和电荷转移--时间分辨光化学和辐射化学实验’)旨在启动巴黎圣母院辐射实验室(NDRL)和莱比锡大学时间分辨光谱(IAG)跨学科研究小组之间的合作。到目前为止，这两个实验室一直独立使用两种最强大的时间分辨光谱技术(即脉冲辐解和闪光光解)，但使用不同的检测方法：IAG的傅里叶变换电子顺磁共振和NRDL的拉曼光谱和电导率测量。独特的方法与IAG在空间受阻酚领域的杰出专业知识和NDRL在电荷和能量转移过程方面的强大背景相结合，有望在一类重要化合物的自由基相关化学方面取得重大进展。