Pericyclic Reactions of Radical Ions

自由基离子的周环反应

• 批准号: 9733050
• 负责人: Olaf Wiest
• 金额: $ 33.8万
• 依托单位: University of Notre Dame
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1998
• 资助国家: 美国
• 起止时间: 1998-04-01 至 2003-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9733050&HistoricalAwards=false
• 关键词: Pericyclic; Reactions; Radical; Ions

The focus of this research is in the area of electron transfer catalysis. A combination of computational and experimental methods will be used to study electrocyclic reactions, electron transfer catalyzed vinycyclopropane rearrangements and the radical cation Bergman cyclization. The educational focus will consist of the development of a course entitled `Computers in Chemistry.` The course links computational chemistry to practical applications and involves industrial participants. With this Faculty Early Development (CAREER) award, the Organic and Macromolecular Chemistry Program is supporting the research and educational activities of Dr. Olaf G. Wiest of the Department of Chemistry at the University of Notre Dame. Professor Wiest will focus his research efforts on the area of electron transfer catalysis. A combination of computational and experimental techniques will help in understanding the role of radical cations in electrocyclic reactions, an important class of organic transformations. The educational activities will focus on the interface between theory and experiment and stresses computational chemistry at the undergraduate and graduate level

本研究的重点是电子转移催化领域。我们将用计算和实验相结合的方法来研究电环反应、电子转移催化的乙烯基环丙烷重排反应和自由基阳离子Bergman环化反应。教育的重点将包括开发一门名为“化学中的计算机”的课程。该课程将计算化学与实际应用联系起来，并有工业参与者参与。凭借这一学院早期发展(职业)奖，有机和高分子化学项目正在支持圣母大学化学系的Olaf G.Wiest博士的研究和教育活动。威斯特教授将把研究重点放在电子转移催化领域。计算和实验技术的结合将有助于理解自由基阳离子在电环反应中的作用，电环反应是一类重要的有机转化。教育活动将集中在理论和实验之间的接口，并强调本科生和研究生水平的计算化学