CAREER: Tripodal Aryloxide Ligands: From Molecular Receptors to Organometallic Catalysis
CAREER: Tripodal Aryloxide Ligands: From Molecular Receptors to Organometallic Catalysis
批准号:
9874966
负责人:
Michael Scott
金额:
$0.0万
依托单位:
依托单位国家:
美国
项目类别:
Continuing grant
财政年份:
1999
资助国家:
美国
项目状态:
已结题
起止时间:
1999-02-15 至 2003-07-31
中文摘要
这个职业奖在无机,生物无机和有机化学计划支持的研究和教育结构定义的配体博士迈克尔斯科特的化学系,佛罗里达大学。 合成了一类新的具有预组装碗状结构的三脚架型芳氧化合物配体。 配体可以通过化学修饰来调节,以选择性地结合各种金属离子或改变它们的反应性。 一些配体具有足够的刚性,使得它们可以用于组装含有金属离子的超分子结构。 配体具有三个结合位点,因此可以将一个以上的金属中心结合到配体骨架上,但寡聚化被抑制。 将制备含铝化合物,其将用作烷基化、环加成和许多其它化学反应的稳健催化剂。 参与该项目的本科生将学习分子识别和催化,以及合成和表征技能。 该职业奖的教育部分将侧重于为生物化学学生开发无机生物化学课程,并在系内提供本科研究课程。
英文摘要
This CAREER award in the Inorganic, Bioinorganic, and Organometallic Chemistry Program supports research and education on structurally defined ligands by Dr. Michael Scott of the Chemistry Department, University of Florida. A new class of tripodal aryloxide ligands with a preorganized bowl-like shape will be synthesized. The ligands can be adjusted by chemical modification to selectively bind various metal ions or to alter their reactivity. Some of the ligands are sufficiently rigid that they can be used in the assembly of supramolecular structures containing metal ions. The ligands have three binding sites and so binding of more than one metal center to the ligand backbone is possible, yet oligomerization is inhibited. Compounds containing aluminum will be prepared which will be useful as robust catalysts for alkylations, cycloadditions and many other chemical reactions. Undergraduate students involved in the project will learn about molecular recognition and catalysis, in addition to skills in synthesis and characterization. The educational component of this CAREER Award will focus on developing a course in inorganic biochemistry for biochemistry students and on offering an undergraduate research course in the department.
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会议论文
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财政年份:2013
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依托单位:
CSR: Small: First-Class Operating System Management of Computational Accelerators
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批准号:1319417
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财政年份:2013
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SHF: Small: Ordering-Based Semantics for Emerging Models of Parallel Computing
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财政年份:2011
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负责人:Michael Scott
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依托单位:
CSR:Small:Parallelism and Concurrency in Scripting Languages
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批准号:1116109
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资助金额:$25.0万
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财政年份:2011
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依托单位:
CCF: Medium: Routine Parallelism Enabled by Speculation
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批准号:0963759
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财政年份:2010
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依托单位:
CAREER: Particle Finite Element Response Sensitivity Analysis of Fluid-Structure Interaction
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批准号:0847055
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财政年份:2009
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负责人:Michael Scott
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依托单位:
A Planning Proposal to Establish a Franco-American Doctoral Student Exchange for Energy and Sustainability
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批准号:0738015
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财政年份:2007
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依托单位:
Religious Language and the Realism Problem
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批准号:113116/1
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项目类别:Research Grant
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资助金额:$1.79万
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财政年份:2006
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负责人:Michael Scott
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依托单位:
CSR--PDOS: Fulfilling the Promise of Transactions in Multithreaded Systems
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批准号:0615139
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财政年份:2006
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负责人:Michael Scott
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依托单位:
Student Travel Support for 19TH ACM Symposium on Operating System Principles (SOSP); Lake George, NY; October 19-22, 2003
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批准号:0335406
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项目类别:Standard Grant
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资助金额:$2.0万
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财政年份:2003
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负责人:Michael Scott
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依托单位:
Extended Structures Built on the Triphenoxymethane Platform: Modeling Metalloenzyme Active Sites
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批准号:0316003
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项目类别:Continuing grant
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资助金额:$0.0万
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财政年份:2003
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负责人:Michael Scott
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依托单位:
High-Performance Synchronization for User-Level Applications
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批准号:0204344
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项目类别:Continuing Grant
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资助金额:$25.26万
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财政年份:2002
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负责人:Michael Scott
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依托单位:
Organometallic Chemistry of Group 6 Imido Diamide Complexes
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批准号:0094404
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项目类别:Continuing Grant
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资助金额:$37.5万
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财政年份:2001
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负责人:Michael Scott
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依托单位:
Experimental Evaluation of Software Coherence for Next-Generation Networks
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批准号:9705594
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项目类别:Continuing Grant
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资助金额:$79.42万
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财政年份:1997
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负责人:Michael Scott
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依托单位:
High-Performance Synchronization for Shared-Memory Parallel Programs
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批准号:9319445
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项目类别:Standard Grant
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资助金额:$18.57万
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财政年份:1994
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负责人:Michael Scott
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依托单位:
Multi-Model Parallel Computing
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批准号:9005633
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项目类别:Standard Grant
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资助金额:$23.39万
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财政年份:1990
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负责人:Michael Scott
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依托单位:
国内基金
海外基金
新型Tripodal氧杂、氮杂醚类化合物的构建以及对阳离子的选择性识别研究
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批准号:20772073
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项目类别:面上项目
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资助金额:28.0万元
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批准年份:2007
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负责人:郭炜
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依托单位: