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Quasi-Two Dimensional Colloid Suspensions

准二维胶体悬浮液

基本信息

批准号：
9977841
负责人：
Stuart Rice
金额：
$ 52.25万
依托单位：
University of Chicago
依托单位国家：
美国
项目类别：
Continuing Grant
财政年份：
1999
资助国家：
美国
起止时间：
1999-09-01 至 2004-02-29
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=9977841&HistoricalAwards=false
关键词：
Quasi Two Dimensional Colloid Suspensions

项目摘要

Stuart Rice is supported by a grant from the Theoretical and Computational Chemistry Program to perform experimental and theoretical studies of the properties of quasi-two dimensional systems. The systems to be studied are suspensions of uncharged monodisperse colloid particles in very thin cells. The proposed experimental studies will be based on digital video microscopy measurements, and use will be made of an optical tweezer to perform trapping experiments. Theoretical simulations will be used to extend the theory of transport in colloid suspensions to include structural fluctuations. Various applications of density functional theory will also be used to study the phase diagram of quasi-two dimensional systems. Particular questions to be addressed include: 1) the changes induced in structures of quasi-two dimensional phases, and the character of the transitions between those phases as a function of constraints associated with confinement; 2) the density dependence of the relaxation processes, and the onset of glass formation; 3) how relaxation processes in colloid suspensions are influenced by a transition from quasi-two dimensional to three dimensional confinement; and 4) how the range of colloid-colloid interaction influences the structure and dynamical behavior of quasi-two dimensional suspensions.The proposed studies will lead to a deeper understanding of the properties of liquid systems that, because they are constrained to two dimensional motion, exhibit unique thermodynamic behavior. This work may have important applications in the development of new materials or specialized devices.

斯图尔特·赖斯得到了理论和计算化学计划的资助，对准二维系统的性质进行实验和理论研究。要研究的体系是不带电荷的单分散胶体颗粒在非常薄的电池中的悬浮液。拟议的实验研究将基于数字视频显微镜测量，并将使用光镊子进行诱捕实验。理论模拟将被用来扩展胶体悬浮液中的输运理论，以包括结构波动。密度泛函理论的各种应用也将被用来研究准二维系统的相图。需要解决的具体问题包括：1)准二维相结构的变化，以及这些相之间的转变作为约束约束的函数的特征；2)弛豫过程的密度依赖性，以及玻璃形成的开始；3)从准二维约束到三维约束的转变如何影响胶体悬浮液中的松弛过程；4)胶体-胶体相互作用的范围如何影响准二维悬浮液的结构和动力学行为。这些研究将加深对液体体系性质的理解，因为它们被限制在二维运动中，表现出独特的热力学行为。这项工作可能在新材料或特殊器件的开发中有重要的应用。