Synthesis of Porous Hybrid Materials based on Layered Silicates: Functional Intercalates, Separation, and Catalysis (A06)

基于层状硅酸盐的多孔杂化材料的合成：功能插层、分离和催化（A06）

• 批准号: 137686907
• 金额: --
• 依托单位: Arbeitsgruppe Anorganische Chemie I
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 财政年份: 2009
• 资助国家: 德国
• 起止时间: 2008-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/137686907?language=en
• 关键词: Synthesis; Porous; Hybrid; Materials; based

An optimized melt synthesis of a charge homogenous hectorite allows for fundamental insights into the process of swelling and provides various ways for the functionalization of internal and external surfaces. A general procedure based on osmotic swelling of 1D-heterostructures makes double stacks and Janus-type platelets accessible. Intercalation of spacers (pillars, nanoparticles) creates micropores materials for gas separation and catalysis. This project explores the application of functionalized colloidal layered silicates derived from various methods of structuring.

电荷均匀锂蒙脱石的优化熔融合成允许对溶胀过程的基本见解，并提供用于内表面和外表面的官能化的各种方式。基于1D-异质结构的渗透溶胀的一般程序使得双堆叠和Janus型血小板可访问。间隔物（柱、纳米颗粒）的嵌入产生用于气体分离和催化的微孔材料。该项目探讨了来自各种结构化方法的功能化胶体层状硅酸盐的应用。