Studies of a Polyoxoanion-Derived, Record Lifetime Dioxygenase Catalyst
多氧阴离子衍生的、创纪录寿命的双加氧酶催化剂的研究
基本信息
- 批准号:0078436
- 负责人:
- 金额:$ 33万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Continuing Grant
- 财政年份:2000
- 资助国家:美国
- 起止时间:2000-08-01 至 2003-07-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This award in the Inorganic, Bioinorganic and Organometallic Chemistry program supports research on the development of polyoxoanion-based dioxygenase catalysts by Professor Richard Finke of the Department of Chemistry at the Colorado State University. A specific focus is the development of new, more robust and longer lifetime dioxygenase catalysts using oxidation-resistant polyoxyanions. The approach involves the performance of kinetic and mechanistic studies of the polyoxoanion-to -dioxygenase catalyst evolution process, isolation and performance of compositional and structural characterization on the true active catalyst, and then the use of the isolated catalyst to extend its applicability to additional classes of reactions for which efficient catalysts do not presently exist.The goal of this research is to develop new catalysts which can directly utilize dioxygen to oxidize a wide variety of aromatics, olefins and alkanes of commercial importance. These catalysts will have a significant economic and environmental impact due to their ability to replace current co-oxidation processes and to their potential applications in the degredation of aromatic pollutants. The students involved in this project will receive broad training in analytical, inorganic and materials chemistry and leave them well-prepared for academic or industrial careers.
科罗拉多州立大学化学系的理查德·芬克教授在无机化学、生物无机化学和金属有机化学项目中获得这一奖项,以支持基于多氧阴离子的双加氧酶催化剂的开发研究。一个特别的焦点是开发使用抗氧化多氧阴离子的新的、更坚固的和更长寿命的双加氧酶催化剂。该方法包括对多氧阴离子转双加氧酶催化剂演化过程的动力学和机理研究,对真实活性催化剂的分离和组成和结构表征的性能,然后利用分离的催化剂将其应用于目前还没有有效催化剂的其他类别的反应。本研究的目标是开发能够直接利用氧气氧化多种具有商业价值的芳烃、烯烃和烷烃的新型催化剂。由于这些催化剂能够取代目前的共氧化过程,并在芳香族污染物脱除方面具有潜在的应用前景,因此它们将对经济和环境产生重大影响。参与该项目的学生将接受分析、无机化学和材料化学方面的广泛培训,为他们的学术或工业生涯做好准备。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Richard Finke其他文献
Richard Finke的其他文献
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{{ truncateString('Richard Finke', 18)}}的其他基金
Photoelectrochemically Driven Water-Oxidation Catalysis by Perylene Diimide Plus Cobalt-Oxide Based Photoanodes: Fundamental Studies En Route to Second-Generation Systems
苝二酰亚胺加氧化钴基光阳极的光电化学驱动水氧化催化:第二代系统的基础研究
- 批准号:
1664646 - 财政年份:2017
- 资助金额:
$ 33万 - 项目类别:
Standard Grant
Water-Oxidation Catalysis by Cobalt Polyoxometalates vs Anion-Stabilized Cobalt-Oxide Nanoparticles: A Critical Comparison En Route to the True, Superior Catalysts
多金属氧酸钴与阴离子稳定的氧化钴纳米颗粒的水氧化催化:在获得真正的优质催化剂的过程中进行关键比较
- 批准号:
1361515 - 财政年份:2014
- 资助金额:
$ 33万 - 项目类别:
Standard Grant
Ziegler-Nanocluster Industrial Catalysts, Part II: Understanding Their Unusual Kinetics, Operando Studies of Key Ir Model and Co Industrial Catalysts, and Enhanced Activity Catalys
齐格勒纳米团簇工业催化剂,第二部分:了解其异常动力学、关键 Ir 模型和 Co 工业催化剂的操作研究以及增强活性催化剂
- 批准号:
1057723 - 财政年份:2011
- 资助金额:
$ 33万 - 项目类别:
Standard Grant
GOALI: 'Ziegler-Nanocluster' Industrial Catalysts Stabilized by Alumoxanes
目标:由铝氧烷稳定的“齐格勒纳米簇”工业催化剂
- 批准号:
0611588 - 财政年份:2006
- 资助金额:
$ 33万 - 项目类别:
Continuing Grant
Discovering Hidden Nanocluster Catalysis
发现隐藏的纳米团簇催化
- 批准号:
0314678 - 财政年份:2003
- 资助金额:
$ 33万 - 项目类别:
Continuing Grant
Polyoxoanion-Supported Transition Metals: Synthesis, Characterization and Applications in Catalysis
多氧阴离子负载的过渡金属:合成、表征及其在催化中的应用
- 批准号:
9531110 - 财政年份:1996
- 资助金额:
$ 33万 - 项目类别:
Continuing Grant
Polyoxoanion-Supported Catalysts: Soluble, Molecular Analogsof Oxide-Supported Heterogeneous Catalysts
多氧阴离子负载的催化剂:氧化物负载的多相催化剂的可溶性分子类似物
- 批准号:
8612924 - 财政年份:1986
- 资助金额:
$ 33万 - 项目类别:
Continuing Grant
Trisubstituted Heteropolytungstates and Catalysis: A New, Soluble Class of Metal Oxide-Supported Catalysts (Chemistry)
三取代杂多钨酸盐和催化:一类新型可溶性金属氧化物负载催化剂(化学)
- 批准号:
8313459 - 财政年份:1983
- 资助金额:
$ 33万 - 项目类别:
Continuing Grant
Synthetic and Mechanistic Organotransition Metal Chemistry: Part I: Heterobimetallic Complexes: Part Ii: Heteropolytungstate Chemistry
有机过渡金属的合成和机械化学:第一部分:异双金属配合物:第二部分:杂多钨酸盐化学
- 批准号:
8018199 - 财政年份:1980
- 资助金额:
$ 33万 - 项目类别:
Continuing Grant
The Preparation and Reactions of New Binuclear Complexes
新型双核配合物的制备及反应
- 批准号:
7811552 - 财政年份:1978
- 资助金额:
$ 33万 - 项目类别:
Standard Grant
相似海外基金
Polyoxoanion-Supported Transition Metals: Synthesis, Characterization and Applications in Catalysis
多氧阴离子负载的过渡金属:合成、表征及其在催化中的应用
- 批准号:
9531110 - 财政年份:1996
- 资助金额:
$ 33万 - 项目类别:
Continuing Grant
Polyoxoanion-Supported Catalysts: Soluble, Molecular Analogsof Oxide-Supported Heterogeneous Catalysts
多氧阴离子负载的催化剂:氧化物负载的多相催化剂的可溶性分子类似物
- 批准号:
8612924 - 财政年份:1986
- 资助金额:
$ 33万 - 项目类别:
Continuing Grant